(1S*,5R*)-9-Phenyl-9-azabicyclo[3.3.1]nonan-3-one

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(1S*,5R*)-9-Phenyl-9-aza­bicyclo­[3.3.1]nonan-3-one

In the title compound, C(14)H(17)NO, the piperidinone and piperidine rings both adopt a chair conformation. The chiral crystals were obtained from a racemic reaction product via spontaneous resolution.

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Phenyl acridine-9-carboxyl­ate

The acridine ring system and the benzene ring in the title compound, C(20)H(13)NO(2), are oriented at a dihedral angle of 6.4 (2)°. The carboxyl group is twisted at an angle of 83.6 (2)° relative to the acridine skeleton. The mol-ecules in the crystal are arranged in stacks along the b axis, with two of the acridine rings involved in multiple π-π inter-actions [centroid-centroid distances in th...

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3,3-Dimethyl-9-phenyl-3,4-dihydro­acridin-1(2H)-one

In the mol-ecule of the title compound, C(21)H(19)NO, the terminal saturated six-membered ring of the dihydro-acridine unit adopts an envelope conformation, while the other two fused rings are nearly coplanar, with a dihedral angle of 2.61 (3)°. The coplanar ring system is oriented with respect to the phenyl ring at a dihedral angle of 74.58 (3)°. In the crystal structure, there is a C-H⋯π cont...

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7-Chloro-3,3-dimethyl-9-phenyl-1,2,3,4-tetra­hydro­acridin-1-one

In the title salt, C(21)H(18)ClNO, the quinoline ring system is approximately planar [maximum deviation = 0.035 (2) Å], and forms a dihedral angle of 71.42 (6)° with the attached phenyl ring. The cyclo-hexa-none ring exists in a half-boat conformation. In the crystal packing, C-H⋯O contacts link the mol-ecules into extended supra-molecular chains along the c axis.

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(2E)-2-Benzyl­idene-9-phenyl-3,4-di­hydro­acridin-1(2H)-one

In the title compound, C26H19NO, the plane of the aromatic heterocycle makes a dihedral angle of 75.22 (4)° with that of the attached phenyl ring. In the crystal, mol-ecules are connected by C-H⋯O inter-actions, generating R 2 (2)(12) dimers. These dimers are further connected by C-H⋯π inter-actions, linking the mol-ecules into chains running along the a-axis direction.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812020065